As I said before, don't attempt to modify anything in /System. Technically it is possible to boot into another OS or recovery and hack it up. But that is simply ridiculous. Learn how the system is supposed to work and just use the facilities that already exist.
To clarify some confusing points:
1) Catalina is a new version of the operating system and is currently in beta.
2) Review point 1 above. This means that THINGS HAVE CHANGED.
3) Apple system files are installed at /
4) User files are installed at /System/Volumes/Data
5) The while filesystem then has a layer of fairy dust applied to make it all look like it did before, with a single / file system
Give point 5 above, all you really need to worry about is that system files are at /System. Files in /Library are technically at /System/Volumes/Data/Library but you can just think of them being at /Library. /Library is therefore mounted read-write and you can modify it as root.
Copy the plist file you want to modify into /Library/LaunchAgents
Make your changes
You will still need to disable SIP to make system changes
sudo launchctl unload -Fw /System/Library/LaunchAgent/com.apple.service.to.hack.up.with.plist
Re-enable SIP
sudo launchctl load -Fw /Library/LaunchAgent/com.apple.service.to.hack.up.with.plist
I just tested this and it seem to work. I didn't actually try to test my hacked up version of fontmover because fontmover is an Apple service and I have no clue what it does. I assume it moves fonts, but I don't know. Hopefully you have more intimate knowledge of the service you are trying to hack up.
Given all the above, I am still curious about why you thought you ever needed to modify files in /System to being with? Are you following instructions on Stack Overflow or some other internet site? Please don't do that! If you weren't already aware, the internet is chock full of misinformation and falsehoods.
You really, really shouldn't be modifying Apple services in the first place. If you do have a legitimate need to do so, you really should be aware of how the operating system has worked for the past several years. If you follow these instructions, you can successfully change the operating system behaviour and your changes should even persist across system updates. I have no doubt that your hacked up plist will likely fail and cause a cascade of other system failures, but that's the risk you take when you start hacking on other people's software.