Solution that worked for me:
Log into appstoreconnect.apple.com
Access your app. Go to TestFlight tab
Locate the group on the left where that user is part of
Remove the user by pressing the checkbox, followed by the "Remove" button
Add the user back by pressing the blue (+) button next to "Testers" header. Choose "Existing" and choose the user from the list.
Their TestFlight should refresh with access to the app.
Topic:
App Store Distribution & Marketing
SubTopic:
TestFlight
Tags: