First, I think you should open a bug report on this if you're seeing a difference between macOS 12 and 13, that should be clarified or investigated.
Next, regarding:
Q1: i will got a 192.0.0.x ip address when i connect to a NAT64 WIFI. So, does the latest macOS/IOS implement CLAT?
I'm not exactly sure what's going on here, it looks like your access point is just vending back an IPv4 address, so possibly when this association was configured iOS just advertised that it supported both addresses and the access point chose IPv4. You should be able to verify this in the logs of the access point.